| hilldeboer.LM {PUPAIM} | R Documentation |
Hill-Deboer Isotherm Linear Analysis
Description
Hill-Deboer isotherm model describes as a case where there is mobile adsorption as well as lateral interaction among molecules.The increased or decreased affinity depends on the kind of force among the adsorption molecules. If there is an attraction between adsorbed molecules, there is an increase in affinity. On the other hand, decreased affinity happens when there is repulsion among the adsorbed molecules.
Usage
hilldeboer.LM(Ce, theta, Temp)
Arguments
Ce |
the numerical value for the equilibrium capacity |
theta |
is the fractional surface coverage |
Temp |
temperature |
Value
the linear regression, parameters for the Hill-Deboer isotherm, and model error analysis
Author(s)
Paul Angelo C. Manlapaz
Chester C. Deocaris
References
De Boer, J. H. (1953). The Dynamical Character of adsorption, Oxford University Press, Oxford, England.
Foo, K. Y., and Hameed, B. H. (2009, September 13). <doi:10.1016/j.cej.2009.09.013> Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal.
Examples
Ce <- c(0.01353, 0.04648, 0.13239, 0.27714, 0.41600, 0.63607,
0.80435, 1.10327, 1.58223)
theta <- c(0.1972984, 0.3487013, 0.6147560, 0.7432401, 0.8854408,
0.8900708, 0.9106746, 0.9106746, 0.9611422)
Temp <- 298.15
hilldeboer.LM(Ce,theta, Temp)